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CH30219: Organic and inorganic aspects of homogeneous catalysis

Follow this link for further information on academic years Academic Year: 2014/5
Further information on owning departmentsOwning Department/School: Department of Chemistry
Further information on credits Credits: 3
Further information on unit levels Level: Honours (FHEQ level 6)
Further information on teaching periods Period: Semester 2
Further information on unit assessment Assessment Summary: EX 100%
Further information on unit assessment Assessment Detail:
  • Examination (EX 100%)
Further information on supplementary assessment Supplementary Assessment: Reassessment exam (where allowed by programme regulations)
Further information on requisites Requisites: Before taking this unit you must take CH20149 or take CH20150 and in taking this unit you cannot take CH40219
Further information on descriptions Description: Aims:
To develop an understanding of homogeneous catalytic transformations involving C=C and C=O bonds, their mechanisms and the importance of the products they generate.

Learning Outcomes:
After studying this Unit, students should be able to:
* Appreciate catalytic cycles and their mechanisms.
* See from both organic and inorganic perspectives how catalytic cycles involving transformations of C=C and C=O bonds occur.
* Appreciate the structures and reactivities of key transition metal intermediates on catalytic cycles.
* Understand how changes of metal-ligand stereoelectronic effects bring about improvements in catalyst activity.

Skills:
Data analysis (T, F, A), problem solving (T, F, A).

Content:
Metal mediated reactions - H-X addition across C=C bonds: hydrogenation, hydrocyanation, conjugate addition. Epoxidation. Ring-opening and -closing metathesis. Transformations with C=O bonds: Methanol carbonylation, ketone hydrogenation, Lewis acid catalysis.
Further information on programme availabilityProgramme availability:

CH30219 is Compulsory on the following programmes:

Department of Chemistry
  • USCH-AFB07 : BSc(Hons) Chemistry for Drug Discovery (Year 3)
  • USCH-AAB08 : BSc(Hons) Chemistry for Drug Discovery with Study year abroad (Year 4)
  • USCH-AFM05 : MChem(Hons) Chemistry for Drug Discovery (Year 3)
  • USCH-AKB08 : BSc(Hons) Chemistry for Drug Discovery with Industrial Placement (Year 4)

CH30219 is Optional on the following programmes:

Department of Chemistry
  • USCH-AFB01 : BSc(Hons) Chemistry (Year 3)
  • USCH-AAB02 : BSc(Hons) Chemistry with Study year abroad (Year 4)
  • USCH-AFM02 : MChem(Hons) Chemistry (Year 3)
  • USCH-AFB09 : BSc(Hons) Chemistry with Education (Year 3)
  • USCH-AKB02 : BSc(Hons) Chemistry with Industrial Placement (Year 4)
  • USCH-AFB03 : BSc(Hons) Chemistry with Management (Year 3)
  • USCH-AAB04 : BSc(Hons) Chemistry with Management with Study year abroad (Year 4)
  • USCH-AFM07 : MSci(Hons) Chemistry with Management (Year 3)
  • USCH-AKB04 : BSc(Hons) Chemistry with Management with Industrial Placement (Year 4)
  • USCH-AKM07 : MSci(Hons) Chemistry with Management with Industrial Placement (Year 4)

Notes:
* This unit catalogue is applicable for the 2014/15 academic year only. Students continuing their studies into 2015/16 and beyond should not assume that this unit will be available in future years in the format displayed here for 2014/15.
* Programmes and units are subject to change at any time, in accordance with normal University procedures.
* Availability of units will be subject to constraints such as staff availability, minimum and maximum group sizes, and timetabling factors as well as a student's ability to meet any pre-requisite rules.