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Waste Management - Hazardous and 'Difficult' Waste

 

 

Categorisation and segregation of hazardous wastes.

Liquid waste streams;
Discharges to drain
Trade Effluent Discharge Consent
Substances prohibited from entry into the sewerage system
Prohibited Substances which must not be disposed of in the general waste bins or down the sink

Low-hazard aqueous waste
Aqueous 'washings'.
Organic solvent waste
Radioactive solvent waste
Spent photographic chemicals
Waste oil

Solid waste streams;
General solid laboratory and workshop waste
Prohibited Substances which must not be disposed of in the general waste bins
Higher-level solid radioactive waste
Glass breakages and disposable laboratory glassware
Clean glass bottles
Fluorescent light tubes and large incandescent lamp bulbs


'Sharps'

Other Clinical waste
Refrigerators and freezers
'Lab smalls
'Special wastes
Asbestos-containing waste
Computer monitors and other hardware


Categorisation and segregation of hazardous wastes.
If you are producing hazardous waste then a risk assessment of the work activity generating such waste must have been completed within your Department or Centre (refer to section 4 part 2.1 of the University Safety Manual). The University (its staff and students) must make every effort to categorise, segregate and contain wastes according to the standards imposed by current legislation and best practice.
If there is any uncertainty about the proper categorisation or method for dealing with a particular waste the Service (Hazardous Waste Service) should be contacted on extension 6540 (01225 386540) or email waste@lists.bath.ac.uk for advice. Since 1992 the duty of care for pollution control and the revision of the associated Regulations has imposed stricter management and documentation procedures. These requirements can only be met by following a scheme of management based on the strict segregation of hazardous wastes from the greater bulk of less harmful material which arises in the University. Such a scheme will also help to minimise the increasingly high costs of waste disposal.


Contaminated and Hazardous Waste Streams.
If you are producing hazardous waste then a risk assessment of the work activity generating such waste must have been completed within your Department or Centre.
For specific wastes go to this table to find the appropriate disposal route.

Laboratory and workshop waste

1.

Low-hazard aqueous waste can be poured down the sink. Dilution to the sewer can be the most appropriate method for disposal of a wide range of materials, particularly organic. Advice can be sought from the Contaminated and Hazardous Waste Service as to whether disposal to drain is appropriate. Some chemicals are prohibited from entering the drainage system and some items are excluded by our trade effluent consent. Very-low-level radioactive aqueous waste must only be poured down designated sinks. The controls stipulated by the Environment Agency mean that radioisotope users are required to log details of such aqueous radioactive waste disposals on the individual radioisotope's track record.
Problems of disposal to drain experienced in the past include those associated with the poor state of repair of the drains in some buildings (the demolished 4W in particular). This is exacerbated with the cavalier use of water vacuum (Venturi) pumps to generate vacuums for filtration and rotary evaporation apparatus where materials which are highly volatile or have a strong stench are being used.
Acetone (used for a final rinse for clean lab glassware) must not be disposed of to drain.
In 2003 there was an explosion in the drainage system here probably caused by acetone vapour.

2.

Aqueous "washings". Due to the recognised poor state of the drainage system in building 4W, aqueous residues from organic solvent extractions were segregated into green-labelled 2.5 litre Winchester bottles. The liquid was disposed to drain, but not in building 4W ( Building 4S was used).
The need for segregation of this waste stream has gone with the relocation of academic departments from 4W .

3.

Organic solvent waste is segregated into 'halogenated' (chlorinated) (yellow-labelled) and 'non-halogenated' (non-chlorinated) (red-labelled) bottles. The Service provides areas generating such hazardous wastes with labelled 2.5 litre glass Winchester bottles. Users should be aware that there is a potential problem when mixing incompatible solvent wastes (such as chloroform and acetone, ethers and ketones, isopropyl alcohol and ketones, nitro compounds and amines). The Service provides labelled bottles with special (vented) caps to release any gradual build-up of pressure. (Look here to see the remains of an exploding waste solvent bottle which didn't have a vented cap and here to see what a splinter of glass did to the window of the lab 10 metres away. The incident happened at night when no-one was in the way!). Contractors bulk the contents of these bottles into 205 litre metal drums, maintaining the segregation between halogenated and non-halogenated. The bottles are re-used for waste solvents. The contaminated solvents are currently sent for use as support fuels in cement kilns.
Acetone (used for a final rinse for clean lab glassware) must not be disposed of to drain. In 2003 there was an explosion in the drainage system here probably caused by acetone vapour.

4.

Radioactive solvent waste (used scintillation vials) is segregated in 60-litre disposable plastic sealable containers which are sent for incineration. The controls stipulated by the Environment Agency mean that users are required to log details of the contents of disposed vials using the radiochemical on-line management system. We have set an upper limit of radioactivity of 4MBq per container.

5.

Spent photographic chemicals (developer and fixer) should be segregated in 25 litre containers (available from the Service) and sent for silver reclamation and proper disposal via the Service.

6.

Waste oil from laboratories and workshops can be collected in suitable (e.g. 5 litre plastic) containers. These are then collected by the Service and decanted into the 205 litre oil drums situated at the rear of building 4 East. This is then taken for recycling. There is also a used oil tank in the students car maintenance area on the University's southern perimeter.

7.

General solid laboratory and workshop waste is essentially low hazard industrial waste and should be placed in "red label bins" (waste-bins with a red label stuck on them). This stream must not contain glass, 'sharps' or 'special waste' and must not be heavily contaminated with hazardous materials. It is likely to comprise items such as paper tissues, filter papers, rubber and plastic tubing, decontaminated plasticware from biological areas and general workshop wastes such as wood, metal and plastic dust and swarf. Some materials must not enter this waste stream. Dusty/powdery materials should be sealed in bags prior to disposal in the 'red label' bins. Very-low-level solid radioactive waste should be disposed via this route. The controls stipulated by the Environment Agency mean that radioisotope users are required to log details of the contents of disposed vials using the radiochemical on-line management system. The porters collect this waste and transfer it to the large industrial waste bins. These are emptied once a week and the contents sent for local landfill. Problems have been experienced in the past with the improper segregation of hazardous waste from this stream (such as hypodermic needles and loose powders).

8.

Higher-level solid radioactive waste is managed by the University's Radiological Protection Officer.

9.

Disposable and broken laboratory glassware is segregated into reusable containers (yellow 10 litre or blue 60 litre) supplied by the Service. These are collected by the Service for disposal as 'special waste' via incineration. This stream must not include iodine, hypodermic needles, sealed ampoules or vials of fluids, capped bottles, reusable/recyclable containers such as milk bottles, coffee jars and wine bottles or laboratory reagent bottles which should be washed, dried and segregated for recycling.

10.

Clean glass bottles should be segregated for recycling. Some laboratory reagent suppliers (such as Merck and Fisher) will take back empty 2.5 litre Winchester bottles. Please contact the Service for details. Most chemical bottles are made from soda glass (low melting temperature) and providing they are clean, have their caps removed and any hazard warning labels have been defaced or removed they can be sent for recycling. Borosilicate laboratory glassware (high melting temperature, e.g. 'Pyrex' and 'Rasotherm') must not be sent for recycling as it can cause very expensive damage to the glass kilns and should be disposed of as described in 9 above. Containers for recycling such bottles are situated in lab prep rooms and/or wash-up areas where these bottles are routinely encountered.

11.

Fluorescent light tubes, ordinary light bulbs and large incandescent lamp bulbs are collected by the Porterage service for recycling. (Fluorescent tubes contain mercury and thay are now classified as `special waste'.)

12.

'Sharps' must be discarded into approved Sharpsbins conforming to BS7320 and UN3291 standards. Such Sharpsbins are available from Central Stores (0.6 litre [code 3 82 2346], 5 litre [code 3 82 2352] and 10 litre [code 3 82 2369]). Sharps comprise items such as hypodermic needles (and attached disposable syringes if removal is inadvisable), small shards of broken glass, mercury-free glass from broken thermometers, scalpel blades and other small sharp items. As long as biological and/or chemical contamination can be rendered harmless, disposable glass Pasteur pipettes can be disposed of as waste glassware (see 8 above) and plastic pipettor tips can be disposed of in the general solid laboratory/workshop waste stream ('red label' as described in 6 above). Sharpsbins are treated as clinical waste no matter from where they originate. Prior to collection Sharpsbins must have their closures secured, should be autoclaved if a biological hazard is present and the tops secured with adhesive packaging tape. They are disposed of via incineration with residues going to landfill. (Guidance on the use of hypodermic needles in laboratories can be found in section 4 part 2.6 of the University Safety Manual.)

13.

Other Clinical waste (animal and human) is segregated in designated freezers for regular collection by a contractor selected by the Service. These streams are incinerated in a 'Waste to Energy' plant.

14.

Refrigerators and freezers are collected from laboratory areas by the Service. These are sent for destruction in approved premises. Units from the residential areas of campus are taken by the local Council waste disposal contractors.

15.

'Lab smalls' are bottles of chemicals, which are surplus to requirements. The Service deals these with twice a year. Disposal of these may be via incineration, landfill or neutralisation. Refer to this link to see more information on this scheme.

16.

'Special wastes' consist of any of the controlled wastes which contain substances or have characteristic properties specified in the Hazardous Waste Regulations 2005. The Environment Agency provide an interpretation of the definition and classification of hazardous waste as an aid to the identification of Hazardous Waste, however all you need to do is contact waste@lists.bath.ac.uk. We produce bulk hazardous waste (silica gel, sand contaminated with crude oil, heavy metal contaminated dry waste) in returnable 120 litre sealable plastic kegs. These are transported by contractors to a transfer station where the kegs are unpacked by hand (so illicit disposals may well be discovered) and the waste transferred to a large skip which is then taken and emptied into a landfill site. We also produce ethidium bromide contaminated waste, antibiotic waste, cytotoxic waste and sealed ampoules (separately segregated) which are contained in 30-litre yellow Medibins and these are sent for incineration. These bins are available from Central Stores (their code number 3 82 2381) and the labels for them can be downloaded from this link. Other Special wastes may be disposed of via incineration, landfill or neutralisation. 

17.

Asbestos-containing waste is managed by the Estates Department.

18.

Personal computers, monitors and associated hardware. These are collected on request and stored on campus. Please refer to this advice to avoid sensitive data being recovered after the removal of storage devices from Departments.


Discharges to drain
Our Trade Effluent Discharge Consent was issued in 1984 by Wessex Water. When the University's effluent reaches the public sewer (under The Avenue, Claverton Down) it must have;

pH not less than 6 or greater than 10

temperature not to exceed 43.3'C (110'F)

there must be no flammable solvents, petroleum or any volatile petroleum products. Suspended solids not to exceed 500 mg/l of effluent

all suspended material to pass through a screen having perforations of 6.5 mm in diameter

grease and oil or fats not to exceed 200 mg/l of effluent

maximum quantity not to exceed 500 cubic metres in a 24 hour period

rate of discharge not to exceed 6 litres per second.


The following are prohibited from entry into the sewerage system
;

petroleum spirit (flammable)

calcium carbide (produces highly flammable acetylene gas on contact with water),

carbon disulphide (highly toxic and flammable) and

organo-halogen compounds, incl. pesticide residues and degreasing agents (toxic).

Problems of disposal to drain experienced in the past include those associated with the poor state of repair of the drains in some buildings (4W in particular). This is exacerbated with the cavalier use of water vacuum (Venturi) pumps to generate vacuums for filtration and rotary evaporation apparatus where materials, which are highly volatile or have a strong stench are being used.

Prohibited Substances, which must not be disposed of in the general waste bins or down the sink;

Antimony (**10mg/l)

Dichlorvos

PCBs (polychlorinated biphenyls)

Arsenic (**10mg/l)

Dioxins

Pentachlorophenol and compounds

Aldrin

Drins (aldrin, dieldrin, endrin)

Petrol

Atrazine

Endosulfan

Selenium (**10mg/l)

Azinphos-ethyl

Fenitrothion

Silver (**10mg/l)

Azinphos-methyl

Fenthion

Simazine

Beryllium (**10mg/l)

HCH (gamma hexachlorocyclo-hexane)

Tetrachloroethylene

Cadmium and compounds

Hexachlorobenzene

Tin (**10mg/l)

Calcium carbide

Hexachlorobutadiene

Tributyl-tin compounds

Carbon disulphide

Lead (**10mg/l)

Trichlorobenzene

Carbon tetrachloride

Malathion

Trichloroethane

Chloroform

Mercury and compounds

Trichloroethylene

Chromium (**10mg/l)

Nickel (**10mg/l)

Trifluralin

Copper (**10mg/l)

Organo-halogen compounds

Triphenyl-tin compounds

DDT

Parathion

Vanadium (**10mg/l)

1,2-Dichloroethane

Parathion-methyl

Zinc (**10mg/l)

** At point of discharge to the public sewer.

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