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Categorisation
and segregation of hazardous wastes.
If you are producing hazardous waste then a risk assessment of the
work activity generating such waste must have been completed within your
Department or Centre (refer to section
4 part 2.1 of the University Safety Manual). The University
(its staff and students) must make every effort to categorise, segregate
and contain wastes according to the standards imposed by current legislation
and best practice.
If there is any uncertainty about the proper categorisation or method
for dealing with a particular waste the Service (Hazardous
Waste Service) should be contacted on extension 6540 (01225 386540) or
email waste@lists.bath.ac.uk
for advice. Since 1992 the duty of care for pollution control and the
revision of the associated Regulations has imposed stricter management
and documentation procedures. These requirements can only be met by following
a scheme of management based on the strict segregation of hazardous
wastes
from the greater bulk of less harmful material which arises in the University.
Such a scheme will also help to minimise the increasingly high costs
of
waste disposal.
Contaminated
and Hazardous Waste
Streams.
If you are producing hazardous waste then a risk assessment of the
work activity generating such waste must have been completed within your
Department or Centre.
For specific wastes go to this table to
find the appropriate disposal route.
Laboratory and workshop waste
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1.
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Low-hazard aqueous waste
can be poured down the sink. Dilution to the sewer can be the most
appropriate method for disposal of a wide range of materials, particularly
organic. Advice can be sought from the Contaminated and Hazardous
Waste Service as to whether disposal to drain is appropriate. Some
chemicals are prohibited from entering the drainage system and
some items are excluded by our trade effluent
consent. Very-low-level radioactive aqueous waste must only
be poured down designated sinks. The controls stipulated by the
Environment Agency mean that radioisotope users are required to
log details of such aqueous radioactive waste disposals on the individual
radioisotope's track record.
Problems of disposal to drain experienced
in the past include those associated with the poor state of repair
of the drains in some buildings (the demolished 4W in particular).
This is exacerbated with the cavalier use of water vacuum (Venturi)
pumps
to generate
vacuums for filtration and rotary evaporation apparatus where materials
which are highly volatile or have a strong stench are being used.
Acetone (used for a final rinse for clean lab glassware) must not
be disposed of to drain. In 2003 there was an explosion
in the drainage system here probably caused by acetone vapour.
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2.
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Aqueous "washings".
Due to the recognised poor state of the drainage system in building
4W, aqueous residues from organic solvent extractions were
segregated into green-labelled 2.5 litre Winchester bottles. The
liquid was disposed to drain, but not in building 4W ( Building
4S was used).
The need for segregation of this waste stream has gone with the
relocation of academic departments from 4W .
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3.
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Organic
solvent waste
is segregated into 'halogenated' (chlorinated) (yellow-labelled)
and 'non-halogenated' (non-chlorinated) (red-labelled) bottles.
The Service provides areas generating such hazardous wastes with
labelled 2.5 litre glass Winchester bottles. Users should be aware
that there is a potential problem when mixing incompatible solvent
wastes (such as chloroform and acetone, ethers and ketones, isopropyl
alcohol and ketones, nitro compounds and amines). The Service provides
labelled bottles with special (vented) caps to release any gradual
build-up of pressure. (Look here
to see the remains of an exploding waste solvent bottle which didn't
have a vented cap and here to
see what a splinter of glass did to the window of the lab 10 metres
away. The incident happened at night when no-one was in the way!).
Contractors bulk the contents of these bottles into 205 litre metal
drums, maintaining the segregation between halogenated and non-halogenated.
The bottles are re-used for waste solvents. The contaminated solvents
are currently sent for use as support fuels in cement kilns.
Acetone (used for a final rinse for clean
lab glassware) must not be disposed of to drain. In 2003
there was an explosion
in the drainage system here probably caused by acetone vapour.
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4.
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Radioactive
solvent waste
(used scintillation vials) is segregated in 60-litre disposable
plastic sealable containers which are sent for incineration.
The
controls stipulated by the Environment Agency mean that users are
required to log details of the contents of disposed vials using
the radiochemical on-line management system. We have set an upper
limit of radioactivity of 4MBq per container.
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5.

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Spent photographic chemicals
(developer and fixer) should be segregated in 25 litre containers
(available from the Service) and sent for silver reclamation
and
proper disposal via the Service.
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6.

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Waste
oil from
laboratories and workshops can be collected in suitable (e.g.
5
litre plastic) containers. These are then collected by the Service
and decanted into the 205 litre oil drums situated at the rear
of building
4
East.
This
is
then
taken for
recycling. There is also a used oil tank in the students car maintenance
area on the University's southern perimeter.
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7.
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General
solid laboratory and workshop waste is
essentially low hazard industrial waste and should be placed in "red
label bins" (waste-bins
with a red label stuck on them). This
stream must not contain glass, 'sharps' or 'special waste' and
must not be heavily contaminated with hazardous materials. It
is
likely to comprise items such as paper tissues, filter papers,
rubber and plastic tubing, decontaminated plasticware from biological
areas
and general workshop wastes such as wood, metal and plastic dust
and swarf. Some materials must not enter
this waste stream. Dusty/powdery materials should be sealed
in bags prior to disposal in the 'red label' bins. Very-low-level
solid
radioactive waste should be disposed via this route. The controls
stipulated by the Environment Agency mean that radioisotope users
are required to log details of the contents of disposed vials using
the radiochemical on-line management system. The porters collect
this waste and
transfer it to the large industrial waste bins. These are emptied
once a week and the contents sent for local landfill. Problems
have been experienced in the past with the improper segregation
of hazardous waste from this stream (such as hypodermic needles
and loose powders).
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8.
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Higher-level
solid radioactive waste is
managed by the University's Radiological Protection Officer.
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9.
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Disposable
and broken laboratory glassware is
segregated into reusable containers (yellow 10 litre or blue 60
litre) supplied by the Service. These are collected
by the Service for disposal as 'special waste' via incineration.
This stream must not include iodine, hypodermic needles, sealed
ampoules or vials of fluids,
capped bottles, reusable/recyclable containers such as milk bottles,
coffee jars and wine bottles or laboratory reagent bottles which
should be washed, dried and segregated for recycling.
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10.

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Clean
glass bottles
should be segregated for recycling. Some laboratory reagent suppliers
(such as Merck and Fisher) will take back empty 2.5 litre Winchester
bottles. Please contact the Service for
details. Most chemical bottles are made from soda glass (low melting
temperature) and providing
they are clean, have their caps removed and any hazard warning
labels have been defaced or removed they can be sent for recycling.
Borosilicate laboratory glassware (high melting temperature, e.g.
'Pyrex' and 'Rasotherm') must not
be sent for recycling as it can cause very expensive damage to
the
glass kilns and should be disposed of as described in 9 above.
Containers for recycling such bottles are situated in lab prep
rooms and/or wash-up
areas where these bottles are routinely encountered.
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11.

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Fluorescent
light tubes, ordinary light bulbs and large incandescent lamp
bulbs are
collected by the Porterage service for recycling. (Fluorescent
tubes contain mercury and thay are now classified as `special
waste'.)
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12.
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'Sharps' must
be discarded into approved Sharpsbins conforming to BS7320 and UN3291
standards. Such Sharpsbins are available from Central
Stores (0.6 litre [code 3 82 2346], 5 litre [code 3 82 2352]
and 10 litre [code 3 82 2369]). Sharps comprise items such as hypodermic
needles (and attached disposable syringes if removal is inadvisable),
small shards of broken glass, mercury-free glass from broken thermometers,
scalpel blades and other small sharp items. As long as biological
and/or chemical contamination can be rendered harmless, disposable
glass Pasteur pipettes can be disposed of as waste glassware (see
8 above) and plastic pipettor tips can be disposed of in the general
solid laboratory/workshop waste stream ('red label' as described
in 6 above). Sharpsbins are treated as clinical waste no matter
from where they originate. Prior to collection Sharpsbins must have
their closures secured, should be autoclaved if a biological hazard
is present and the tops secured with adhesive packaging tape. They
are disposed of via incineration with residues going to landfill.
(Guidance on the use of hypodermic needles in laboratories can
be found in section
4 part 2.6 of the University Safety Manual.)
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13.

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Other Clinical waste (animal
and human) is segregated in designated freezers for regular collection
by a contractor selected by the Service. These streams are incinerated
in a 'Waste to Energy' plant.
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14.

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Refrigerators
and freezers
are collected from laboratory areas by the Service. These are sent
for destruction in approved premises. Units from the residential
areas of campus
are taken by the local Council waste disposal contractors.
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15.
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'Lab smalls' are
bottles of chemicals, which are surplus to requirements. The Service
deals these with twice a year. Disposal of these may be via incineration,
landfill or neutralisation. Refer to this
link to see more information on this scheme.
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16.
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'Special wastes'
consist of any of the controlled wastes which contain substances
or have characteristic properties specified in the Hazardous
Waste Regulations 2005. The Environment Agency provide an
interpretation of the definition and classification of hazardous
waste as an aid to the identification of Hazardous Waste, however
all you need to do is contact waste@lists.bath.ac.uk.
We produce bulk hazardous waste (silica gel, sand contaminated with
crude oil, heavy metal contaminated dry waste) in returnable 120
litre sealable plastic kegs. These are transported by contractors
to a transfer station where the kegs are unpacked by hand (so illicit
disposals may well be discovered) and the waste transferred to a
large skip which is then taken and emptied into a landfill site.
We also produce ethidium bromide contaminated waste, antibiotic
waste, cytotoxic waste and sealed ampoules (separately segregated)
which are contained in 30-litre yellow Medibins and these are sent
for incineration. These bins are available from Central Stores (their
code number 3 82 2381) and the labels for them can be downloaded
from this
link. Other Special wastes may be disposed of via incineration,
landfill or neutralisation.
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17.
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Asbestos-containing waste
is managed by the Estates
Department.
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18.

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Personal
computers, monitors and associated hardware. These
are collected on request and stored on campus. Please refer
to this
advice to avoid sensitive data being recovered after the removal
of storage devices from Departments. |
Discharges
to drain
Our Trade Effluent Discharge Consent
was issued in 1984 by Wessex
Water. When the University's effluent reaches the public sewer (under
The Avenue, Claverton Down) it must have;
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pH not less than 6 or greater than 10
temperature not to exceed 43.3'C (110'F)
there must be no flammable solvents, petroleum or
any volatile petroleum products. Suspended solids not to exceed
500 mg/l of effluent
all suspended material to pass through a screen
having perforations of 6.5 mm in diameter
grease and oil or fats not to exceed 200 mg/l of
effluent
maximum quantity not to exceed 500 cubic metres
in a 24 hour period
rate of discharge not to exceed 6 litres per second.
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The following are prohibited from entry into the sewerage system;
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petroleum spirit (flammable)
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calcium carbide (produces
highly flammable acetylene gas on contact with water),
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carbon disulphide (highly
toxic and flammable) and
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organo-halogen compounds,
incl. pesticide residues and degreasing agents (toxic).
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Problems of disposal to drain experienced in the past include
those associated with the poor state of repair of the drains in some buildings
(4W in particular). This is exacerbated with the cavalier use of water
vacuum (Venturi) pumps to generate vacuums for filtration and rotary evaporation
apparatus where materials, which are highly volatile or have a strong
stench are being used.
Prohibited Substances, which must
not be disposed of in the general waste bins or down the sink;
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Antimony (**10mg/l)
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Dichlorvos
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PCBs (polychlorinated biphenyls)
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Arsenic (**10mg/l)
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Dioxins
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Pentachlorophenol and compounds
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Aldrin
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Drins (aldrin, dieldrin, endrin)
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Petrol
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Atrazine
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Endosulfan
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Selenium (**10mg/l)
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Azinphos-ethyl
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Fenitrothion
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Silver (**10mg/l)
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Azinphos-methyl
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Fenthion
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Simazine
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Beryllium (**10mg/l)
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HCH (gamma hexachlorocyclo-hexane)
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Tetrachloroethylene
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Cadmium and compounds
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Hexachlorobenzene
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Tin (**10mg/l)
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Calcium carbide
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Hexachlorobutadiene
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Tributyl-tin compounds
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Carbon disulphide
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Lead (**10mg/l)
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Trichlorobenzene
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Carbon tetrachloride
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Malathion
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Trichloroethane
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Chloroform
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Mercury and compounds
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Trichloroethylene
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Chromium (**10mg/l)
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Nickel (**10mg/l)
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Trifluralin
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Copper (**10mg/l)
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Organo-halogen compounds
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Triphenyl-tin compounds
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DDT
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Parathion
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Vanadium (**10mg/l)
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1,2-Dichloroethane
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Parathion-methyl
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Zinc (**10mg/l)
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** At point of discharge to the public sewer.
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