 Academic Year:
| 2012/3 |
| Owning Department/School:
| Department of Chemistry |
| Credits:
| 3 |
| Level:
| Honours (FHEQ level 6) |
| Period: |
Semester 2
|
| Assessment:
| EX 100% |
| Supplementary Assessment: | Like-for-like reassessment (where allowed by programme regulations) |
| Requisites:
| Before taking this unit you must take CH20147 or take CH20148 and in taking this unit you cannot take CH40064 |
| Description:
| Aims & Learning Objectives:
To look at chemistry `beyond the molecule' and how a variety of intermolecular interactions can be exploited in terms of molecular recognition both in solution and in the solid state.
After studying this Unit, students should be able to:
* describe some important examples of host-guest chemistry.
* relate the self-organisation of simple molecules to the wider aspects of chemistry.
* highlight future applications of supramolecular chemistry.
Content:
Introduction to supramolecular chemistry - concepts of molecular recognition, self-assembly, complementarity and receptor-substrate relationships. Host-guest chemistry. Cation and anion recognition and molecular sensors. Catenanes and rotaxanes. Molecular machines and supramolecular catalysis. Ligand design - steric and electronic effects. Use of coordination to control shape. Helices, squares and grids. Coordination polymers. Hydrogen bonding - introduction, molecular recognition and crystal engineering. Weaker interactions - p-p stacking C-H...O interactions and d¹º - d¹º interactions (aurophilicity).
|
Programme availability:
|
CH30064 is Optional on the following programmes:
Department of Chemistry
- USCH-AFB01 : BSc (hons) Chemistry (Full-time) - Year 3
- USCH-AFB07 : BSc (hons) Chemistry for Drug Discovery (Full-time) - Year 3
- USCH-AKB08 : BSc (hons) Chemistry for Drug Discovery with Industrial Training (Full-time with Thick Sandwich Placement) - Year 4
- USCH-AAB08 : BSc (hons) Chemistry for Drug Discovery with Study Year abroad (Full-time with Study Year Abroad) - Year 4
- USCH-AFB09 : BSc (hons) Chemistry with Education (Full-time) - Year 3
- USCH-AKB02 : BSc (hons) Chemistry with Industrial Training (Full-time with Thick Sandwich Placement) - Year 4
- USCH-AFB03 : BSc (hons) Chemistry with Management (Full-time) - Year 3
- USCH-AKB04 : BSc (hons) Chemistry with Management with Industrial Training (Full-time with Thick Sandwich Placement) - Year 4
- USCH-AAB04 : BSc (hons) Chemistry with Management with Study Year Abroad (Full-time with Study Year Abroad) - Year 4
- USCH-AAB02 : BSc (hons) Chemistry with Study Year abroad (Full-time with Study Year Abroad) - Year 4
- USCH-AFM02 : MChem (hons) Chemistry (Full-time) - Year 3
- USCH-AFM05 : MChem (hons) Chemistry for Drug Discovery (Full-time) - Year 3
- USCH-AFM07 : MSci (hons) Chemistry with Management (Full-time) - Year 3
- USCH-AKM07 : MSci (hons) Chemistry with Management with Industrial Training (Full-time with Thick Sandwich Placement) - Year 4
Programmes in Natural Sciences
- UXXX-AFB01 : BSc (hons) Natural Sciences (Full-time) - Year 3
- UXXX-AKB02 : BSc (hons) Natural Sciences with Industrial Placement (Full-time with Thick Sandwich Placement) - Year 4
- UXXX-AAB02 : BSc (hons) Natural Sciences with Study Year Abroad (Full-time with Study Year Abroad) - Year 4
- UXXX-AFM01 : MSci (hons) Natural Sciences (Full-time) - Year 3
- UXXX-AKM02 : MSci (hons) Natural Sciences with Professional Placement (Full-time with Thick Sandwich Placement) - Year 4
- UXXX-AAM02 : MSci (hons) Natural Sciences with Study Year Abroad (Full-time with Study Year Abroad) - Year 4
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