CH40211: Chemistry beyond the molecule
Academic Year: | 2019/0 |
Owning Department/School: | Department of Chemistry |
Credits: | 3 [equivalent to 6 CATS credits] |
Notional Study Hours: | 60 |
Level: | Masters UG & PG (FHEQ level 7) |
Period: |
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Assessment Summary: | CW 10%, EX-TH 90%* |
Assessment Detail: |
*Assessment updated due to Covid-19 disruptions |
Supplementary Assessment: |
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Requisites: |
Before taking this module you must take CH20149 OR take CH20150
In taking this module you cannot take CH30211 |
Description: | Aims: To teach aspects of supramolecular chemistry with an emphasis on (bio)chemical recognition and sensing. Learning Outcomes: After taking this course the student should be able to: * Identify and discriminate the relevant supramolecular interactions based on the solvent system; * Describe analytical techniques used to investigate supramolecular interactions; * Understand the role of solvation in molecular recognition and chemical reactivity; * Describe dynamic combinatorial chemistry; * Explain the enthalpic and entropic contributions in molecular recognition; * Identify and describe different types of sensors; * Design basic on/off and off/on molecular sensors; * Explain the difference between sensing and sequestering; * Describe molecular carriers and cellular channels and their mode of action; * Solve unseen problems relating to supramolecular chemistry; * Critically evaluate examples of supramolecular chemistry from the current literature. Skills: Learning and studying T/F/A, Written communication T/F/A, Numeracy & computation T/F/A, Problem solving T/F, Information handling & retrieval T/F/A, Working independently T/F, Career preparation T/F. Content: Supramolecular Chemistry: Concepts and definition; Classification of supramolecular interactions; Cooperativity, effective molarity and chelate effect; Highlights of supramolecular interactions in nature. Solvation and solvophobic effects. Characterisation of supramolecular systems. Supramolecular chemistry through design: Small molecule receptors; Small molecule guests for biological targets; Supramolecular polymers. Dynamic combinatorial chemistry: Types of reversible chemistry; Analytical methods. Solution Host-Guest Chemistry: Cation receptors; Anion receptors; Neutral molecule receptors; Ditopic receptors. Sensors. Natural and artificial channels. |
Programme availability: |
CH40211 is Optional on the following programmes:Department of Chemistry
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Notes:
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