Academic Year: | 2018/9 |
Owning Department/School: | Department of Chemistry |
Credits: | 3 [equivalent to 6 CATS credits] |
Notional Study Hours: | 60 |
Level: | Honours (FHEQ level 6) |
Period: |
- Semester 1
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Assessment Summary: | EX 100% |
Assessment Detail: | |
Supplementary Assessment: |
- Like-for-like reassessment (where allowed by programme regulations)
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Requisites: |
Before taking this module you must take CH20147 OR take CH20148
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Description:
| Aims: To introduce the principles of the chemistry of the 4f and 5f series of elements (lanthanides and actinides).
Learning Outcomes: After studying the Unit, students should be able to:
* explain the importance of the 4f and 5f valence orbitals in determining the chemistry (and contrasts between the chemistries ) of the lanthanide and actinide elements;
* describe variations in oxidation state and the uses of coordination and solid state f-element compounds in synthesis and catalysis;
* rationalise the magnetic and spectroscopic behaviour of the f-elements and explain how these properties are exploited in a variety of applications;
* describe and explain the formation (or lack of formation) of multiple bonds to 4f and f element centres.
Skills: Problem solving (T, F, A)
Independent working (F)
Content: Introduction to the 4f elements, the lanthanides. Shapes and nature of the f-orbitals. Oxidation states and effects of the lanthanide contraction.
Extraction and isolation of the lanthanides. Solid state 4f element compounds, halides and oxides.
Divalent and tetravalent lanthanide compounds. Electronic configurations, magnetism and spectroscopy of lanthanide derivatives. Lanthanide coordination chemistry and shift reagents and use in organic synthesis. Organolanthanide chemistry and organometallic catalysis.
Actinide occurrence and synthesis. The 5f orbitals; comparison to lanthanide chemistry. Applications of actinide elements. Actinide oxidation states and coordination chemistry. Actinide spectroscopy and magnetism. Actinide organometallic chemistry.
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Programme availability: |
CH30127 is Compulsory on the following programmes:
Department of Chemistry
- USCH-AFB01 : BSc(Hons) Chemistry (Year 3)
- USCH-AAB02 : BSc(Hons) Chemistry with Study year abroad (Year 4)
- USCH-AFB07 : BSc(Hons) Chemistry for Drug Discovery (Year 3)
- USCH-AAB08 : BSc(Hons) Chemistry for Drug Discovery with Study year abroad (Year 4)
- USCH-AKB08 : BSc(Hons) Chemistry for Drug Discovery with Industrial Placement (Year 4)
- USCH-AKB02 : BSc(Hons) Chemistry with Industrial Placement (Year 4)
- USCH-AFM02 : MChem(Hons) Chemistry (Year 3)
CH30127 is Optional on the following programmes:
Department of Chemistry
- USCH-AFB03 : BSc(Hons) Chemistry with Management (Year 3)
- USCH-AAB04 : BSc(Hons) Chemistry with Management with Study year abroad (Year 4)
- USCH-AKB04 : BSc(Hons) Chemistry with Management with Industrial Placement (Year 4)
- USCH-AFM05 : MChem(Hons) Chemistry for Drug Discovery (Year 3)
- USCH-AFM07 : MSci(Hons) Chemistry with Management (Year 3)
- USCH-AKM07 : MSci(Hons) Chemistry with Management with Industrial Placement (Year 4)
Programmes in Natural Sciences
- UXXX-AFB01 : BSc(Hons) Natural Sciences (Biochemistry with Chemistry stream) (Year 3)
- UXXX-AAB02 : BSc(Hons) Natural Sciences (Biochemistry with Chemistry stream) with Study year abroad (Year 4)
- UXXX-AKB02 : BSc(Hons) Natural Sciences (Biochemistry with Chemistry stream) with Year long work placement (Year 4)
- UXXX-AFB01 : BSc(Hons) Natural Sciences (Biology with Chemistry stream) (Year 3)
- UXXX-AAB02 : BSc(Hons) Natural Sciences (Biology with Chemistry stream) with Study year abroad (Year 4)
- UXXX-AKB02 : BSc(Hons) Natural Sciences (Biology with Chemistry stream) with Year long work placement (Year 4)
- UXXX-AFB01 : BSc(Hons) Natural Sciences (Chemistry with Biochemistry stream) (Year 3)
- UXXX-AAB02 : BSc(Hons) Natural Sciences (Chemistry with Biochemistry stream) with Study year abroad (Year 4)
- UXXX-AKB02 : BSc(Hons) Natural Sciences (Chemistry with Biochemistry stream) with Year long work placement (Year 4)
- UXXX-AFB01 : BSc(Hons) Natural Sciences (Chemistry with Biology stream) (Year 3)
- UXXX-AAB02 : BSc(Hons) Natural Sciences (Chemistry with Biology stream) with Study year abroad (Year 4)
- UXXX-AKB02 : BSc(Hons) Natural Sciences (Chemistry with Biology stream) with Year long work placement (Year 4)
- UXXX-AFB01 : BSc(Hons) Natural Sciences (Chemistry with Pharmacology stream) (Year 3)
- UXXX-AAB02 : BSc(Hons) Natural Sciences (Chemistry with Pharmacology stream) with Study year abroad (Year 4)
- UXXX-AKB02 : BSc(Hons) Natural Sciences (Chemistry with Pharmacology stream) with Year long work placement (Year 4)
- UXXX-AFB01 : BSc(Hons) Natural Sciences (Chemistry with Physics stream) (Year 3)
- UXXX-AAB02 : BSc(Hons) Natural Sciences (Chemistry with Physics stream) with Study year abroad (Year 4)
- UXXX-AKB02 : BSc(Hons) Natural Sciences (Chemistry with Physics stream) with Year long work placement (Year 4)
- UXXX-AFB01 : BSc(Hons) Natural Sciences (Environmental Science with Chemistry stream) (Year 3)
- UXXX-AAB02 : BSc(Hons) Natural Sciences (Environmental Science with Chemistry stream) with Study year abroad (Year 4)
- UXXX-AKB02 : BSc(Hons) Natural Sciences (Environmental Science with Chemistry stream) with Year long work placement (Year 4)
- UXXX-AFB01 : BSc(Hons) Natural Sciences (Pharmacology with Chemistry stream) (Year 3)
- UXXX-AAB02 : BSc(Hons) Natural Sciences (Pharmacology with Chemistry stream) with Study year abroad (Year 4)
- UXXX-AKB02 : BSc(Hons) Natural Sciences (Pharmacology with Chemistry stream) with Year long work placement (Year 4)
- UXXX-AFB01 : BSc(Hons) Natural Sciences (Physics with Chemistry stream) (Year 3)
- UXXX-AAB02 : BSc(Hons) Natural Sciences (Physics with Chemistry stream) with Study year abroad (Year 4)
- UXXX-AKB02 : BSc(Hons) Natural Sciences (Physics with Chemistry stream) with Year long work placement (Year 4)
- UXXX-AFM01 : MSci(Hons) Natural Sciences (Biochemistry with Chemistry stream) (Year 3)
- UXXX-AAM02 : MSci(Hons) Natural Sciences (Biochemistry with Chemistry stream) with Study year abroad (Year 4)
- UXXX-AKM02 : MSci(Hons) Natural Sciences (Biochemistry with Chemistry stream) with Professional Placement (Year 4)
- UXXX-AFM01 : MSci(Hons) Natural Sciences (Biochemistry with Pharmacology stream) (Year 3)
- UXXX-AAM02 : MSci(Hons) Natural Sciences (Biochemistry with Pharmacology stream) with Study year abroad (Year 4)
- UXXX-AKM02 : MSci(Hons) Natural Sciences (Biochemistry with Pharmacology stream) with Professional Placement (Year 4)
- UXXX-AFM01 : MSci(Hons) Natural Sciences (Biology with Chemistry stream) (Year 3)
- UXXX-AAM02 : MSci(Hons) Natural Sciences (Biology with Chemistry stream) with Study year abroad (Year 4)
- UXXX-AKM02 : MSci(Hons) Natural Sciences (Biology with Chemistry stream) with Professional Placement (Year 4)
- UXXX-AFM01 : MSci(Hons) Natural Sciences (Biology with Pharmacology stream) (Year 3)
- UXXX-AAM02 : MSci(Hons) Natural Sciences (Biology with Pharmacology stream) with Study year abroad (Year 4)
- UXXX-AKM02 : MSci(Hons) Natural Sciences (Biology with Pharmacology stream) with Professional Placement (Year 4)
- UXXX-AFM01 : MSci(Hons) Natural Sciences (Chemistry with Biochemistry stream) (Year 3)
- UXXX-AAM02 : MSci(Hons) Natural Sciences (Chemistry with Biochemistry stream) with Study year abroad (Year 4)
- UXXX-AKM02 : MSci(Hons) Natural Sciences (Chemistry with Biochemistry stream) with Professional Placement (Year 4)
- UXXX-AFM01 : MSci(Hons) Natural Sciences (Chemistry with Biology stream) (Year 3)
- UXXX-AAM02 : MSci(Hons) Natural Sciences (Chemistry with Biology stream) with Study year abroad (Year 4)
- UXXX-AKM02 : MSci(Hons) Natural Sciences (Chemistry with Biology stream) with Professional Placement (Year 4)
- UXXX-AFM01 : MSci(Hons) Natural Sciences (Chemistry with Pharmacology stream) (Year 3)
- UXXX-AAM02 : MSci(Hons) Natural Sciences (Chemistry with Pharmacology stream) with Study year abroad (Year 4)
- UXXX-AKM02 : MSci(Hons) Natural Sciences (Chemistry with Pharmacology stream) with Professional Placement (Year 4)
- UXXX-AFM01 : MSci(Hons) Natural Sciences (Chemistry with Physics stream) (Year 3)
- UXXX-AAM02 : MSci(Hons) Natural Sciences (Chemistry with Physics stream) with Study year abroad (Year 4)
- UXXX-AKM02 : MSci(Hons) Natural Sciences (Chemistry with Physics stream) with Professional Placement (Year 4)
- UXXX-AFM01 : MSci(Hons) Natural Sciences (Physics with Chemistry stream) (Year 3)
- UXXX-AAM02 : MSci(Hons) Natural Sciences (Physics with Chemistry stream) with Study year abroad (Year 4)
- UXXX-AKM02 : MSci(Hons) Natural Sciences (Physics with Chemistry stream) with Professional Placement (Year 4)
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